<?xml version="1.0" encoding="utf-8" standalone="no"?>
<!DOCTYPE article SYSTEM "http://www.atmos-meas-tech.net/inc/amt/copernicus.dtd">
<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques</journal_title>
		<journal_url>www.atmos-meas-tech.net</journal_url>
		<issn>1867-1381</issn>
		<eissn>1867-8548</eissn>
		<volume_number>1</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/amt-1-1-2008</doi>
	<article_url>http://www.atmos-meas-tech.net/1/1/2008/</article_url>
	<abstract_html>http://www.atmos-meas-tech.net/1/1/2008/amt-1-1-2008.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech.net/1/1/2008/amt-1-1-2008.pdf</fulltext_pdf>
	<start_page>1</start_page>
	<end_page>8</end_page>
	<publication_date>2008-10-29</publication_date>
	<article_title content_type="html">Surface features on Sahara soil dust particles made visible by atomic force microscope (AFM) phase images</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>G. Helas</name>
			<email>gth@mpch-mainz.mpg.de</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>M. O. Andreae</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Max Planck Institute for Chemistry, Biogeochemistry Department, P.O.Box 3060, 5020 Mainz, Germany</affiliation>
	</affiliations>
	<abstract content_type="html">We show that atomic force microscopy (AFM) phase images can reveal surface
features of soil dust particles, which are not evident using other
microscopic methods. The non-contact AFM method is able to resolve
topographical structures in the nanometer range as well as to uncover
repulsive atomic forces and attractive van der Waals&apos; forces, and thus gives
insight to surface properties. Though the method does not allow quantitative
assignment in terms of chemical compound description, it clearly shows
deposits of distinguishable material on the surface. We apply this technique
to dust aerosol particles from the Sahara collected over the Atlantic Ocean
and describe micro-features on the surfaces of such particles.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Andreae, M. O., Charlson, R. J., Bruynseels, F., Storms, H., van Grieken, R. E., and Maenhaut, W.: Internal mixture of sea salt, silicates and excess sulfate in marine aerosols, Science, 232, 1620–1623, 1986. </reference>
		<reference numeration="2" content_type="text"> Andreae, M. O., Andreae, T. W., Meyerdierks, D., and Thiel, C.: Marine sulfur cycling and the atmospheric aerosol over the springtime North Atlantic, Chemosphere, 52, 1321–1343, 2003. </reference>
		<reference numeration="3" content_type="text"> Barkay, Z., Teller, A., Ganor, E., Levin, Z., and Shapira, Y.: Atomic force and scanning electron microscopy, Microsc. Res. Techniq., 68, 107–114, 2005. </reference>
		<reference numeration="4" content_type="text"> Bonnell, D.: Scanning Probe Microscopy: Theory, Techniques, and Applications, Wiley-VCH, New York, USA, p 493, 2001. </reference>
		<reference numeration="5" content_type="text"> Bosbach, D. and Enders, M.: Microtopography of high-calcium fly ash particle surfaces, Adv. Cem. Res., 10, 17–23, 1998. </reference>
		<reference numeration="6" content_type="text"> Brandsch, R., Bar, G., and Whangbo, M.-H.: On the factors affecting the contrast of height and phase images in tapping mode atomic force microscopy, Langmuir, 13, 6349–6353, 1997. </reference>
		<reference numeration="7" content_type="text"> Carvalho, M. C. N. A., Perez, C. A., Simão, Passos, F. B., and Schmal, M.: The promoting effect of cesium structure and morphology of silver catalysts, An. Acad. Bras. Ciências 76, 19–27, 2004. </reference>
		<reference numeration="8" content_type="text"> Dokou, E., Stangland, E. E., Andres, R. P., Delgass, W. N., and Barteau, M. A.: Comparison of AFM and HRTEM to determine the metal particle morphology and loading of an Au/TiO&lt;sub&gt;2&lt;/sub&gt; catalyst, Catal. Lett., 70, 1–7, 2000. </reference>
		<reference numeration="9" content_type="text"> Dauphin, Y., Guzman, N., Denis, A., Cuif, J.-P., and Ortlieb, L.: Microstructure, nanostructure and composition of the shell of \textitConcholepas concholepas (Gastropoda, Muricidae), Aquat. Living Resour., 16, 95–103, 2003. </reference>
		<reference numeration="10" content_type="text"> Demanet, C. M.: Atomic force microscopy determination of the topography of fly-ash particles, Appl. Surf. Sci., 89, 97–101, 1995. </reference>
		<reference numeration="11" content_type="text"> Falkovich, A. H., Ganor, E., Levin, Z., Formenti, P., and Rudich, Y.: Chemical and mineralogical analysis of individual mineral dust particles, J. Geophys. Res., 106, 18 029–18 036, 2001. </reference>
		<reference numeration="12" content_type="text"> Friedbacher, G., Grasserbauer, M., Mesimani, Y., Klaus, N., and Higatsberger, J.: Investigation of environmental aerosol by atomic force microscopy, Anal. Chem., 67, 1749–1754, 1995. </reference>
		<reference numeration="13" content_type="text"> García, R. and Pérez, R.: Dynamic atomic force microscopy methods, Surf. Sci. Rep., 47, 197–301, 2002. </reference>
		<reference numeration="14" content_type="text"> Giessibl, F. J.: Atomic resolution of the silicon (111)-(7x7) surface by atomic force microscopy, Science, 267, 68–71, 1995. </reference>
		<reference numeration="15" content_type="text"> Goldstein, J. I., Newbury, D. E., Echlin, P., Joy, D. C., Romig Jr., A. D., Lyman, C. E., Fiori, C., and Lifshin, E.: Scanning electron microscopy and X-ray microanalysis, Plenum Press, New York, USA, 1992. </reference>
		<reference numeration="16" content_type="text"> Gwaze, P., Annegarn, H. J., Huth, J., Helas, G.: Comparison of particle sizes with impactor, AFM and SEM, Atmos. Res., 86, 93–104, 2007. </reference>
		<reference numeration="17" content_type="text"> James, P. J., Antognozzi, M., Tamayo, J., McMaster, T. J., Newton, J. M., and Miles, M. J.: Interpretation of contrast in tapping mode AFM and shear force microscopy. A study on Nafion, Langmuir, 17, 349–360, 2001. </reference>
		<reference numeration="18" content_type="text"> Kojima, T., Buseck, P. R., Iwasaka, Y., Matsuki, A., and Trochkine, D.: Sulfate-coated dust particles in the free troposphere over Japan, Atmos. Res., 82, 698–708, 2006. </reference>
		<reference numeration="19" content_type="text"> Köllensperger, G., Friedbacher, G., Grasserbauer, M., and Dorffner, L.: Investigation of aerosol particles by atomic force microscopy, Fresenius J. Anal. Chem., 358, 268–273, 1997. </reference>
		<reference numeration="20" content_type="text"> Köllensperger, G., Friedbacher, G., Grasserbauer, M., and Dorffner, L.: \textitIn-situ investigation of aerosol particles by atomic force microscopy, Fresenius J. Anal. Chem., 361, 716–721, 1998. </reference>
		<reference numeration="21" content_type="text"> Köllensperger, G., Friedbacher, G., Kotzick, R., Niessner, R., and Grasserbauer, M.: In-situ atomic force microscopy investigation of aerosols exposed to different humidities, Fresenius J. Anal. Chem., 364, 296–304, 1999. </reference>
		<reference numeration="22" content_type="text"> Kühle, A., Sørensen, A. H., and Bohr, J.: Role of attractive forces in tapping tip force microscopy, J. Appl. Phys., 81, 6562–6569, 1997. </reference>
		<reference numeration="23" content_type="text"> Lehmpuhl, D. W., Ramirez-Aguilar, K. A., Michel, A. E., Rowlen, K. L., and Birks, J. W.: Physical and chemical characterization of atmospheric aerosols by atomic force microscopy, Anal. Chem., 71, 379–383, 1999. </reference>
		<reference numeration="24" content_type="text"> Levin, Z., Ganor, E., and Gladstein, V.: The effects of desert particles coated with sulfate on rain formation in the eastern Mediterranean, J. Appl. Meteorol., 35, 1511–1522, 1996. </reference>
		<reference numeration="25" content_type="text"> Morita, S., Wiesendanger, R., and Meyers, E. (Eds.): Noncontact atomic force microscopy, Springer, Berlin, 439 pp., 2002. </reference>
		<reference numeration="26" content_type="text"> Magonov, S. N., Elings, B., and Whangbo, M.-H.: Phase imaging and stiffness in tapping-mode atomic force microscopy, Surf. Sci., 375, L385–L391, 1997. </reference>
		<reference numeration="27" content_type="text"> Martin, Y., Abraham, D. W., and Wickramasinghe, H. K.: High-resolution capacitance measurement and potentiometry by force microscopy, Appl. Phys. Lett., 52, 1103–1105, 1988. </reference>
		<reference numeration="28" content_type="text"> Na, C., Kendall, T. A., and Martin, S. T.: Surface-potential heterogeneity of reacted calcite and rhodochrosite, Environ. Sci. Technol., 41, 6491–6497, 2007. </reference>
		<reference numeration="29" content_type="text"> Nonnenmacher, M., O&apos;Boyle, M. P., and Wickramasinghe, H. K.: Kelvin probe force microscopy, Appl. Phys. Lett., 58, 2921–2923, 1991. </reference>
		<reference numeration="30" content_type="text"> Pósfai, M., Xu, H., Anderson, J. R., and Buseck, P. R.: Wet and dry sizes of atmospheric aerosol particles: An AFM-TEM study, Geophys. Res. Lett., 25, 1907–1910, 1998. </reference>
		<reference numeration="31" content_type="text"> Ramirez-Aguilar, K. A., Lehmpuhl, D. W., Michel, A. E., Birks, J. W., and Rowlen, K. L.: Atomic force microscopy for the analysis of environmental particles, Ultramicroscopy, 77, 187–194, 1999. </reference>
		<reference numeration="32" content_type="text"> Semeniuk, T. A., Wise, M. E., Martin, S. T., Russell, L. M., and Puseck, P. R.: Water uptake characteristics of individual atmospheric particles having coatings, Atmos. Environ., 41, 6225–6235, 2007. </reference>
		<reference numeration="33" content_type="text"> Sokolov, I. Yu. and Henderson, G. S.: The height dependence of image contrast when imaging by non-contact AFM, Surf. Sci., 464, L745–L751, 2000. </reference>
		<reference numeration="34" content_type="text"> Sokolov, I. Yu., Henderson, G. S., and Wicks, F. J.: Force spectroscopy in noncontact mode, Appl. Surf. Sci., 140, 358–361, 1999. </reference>
		<reference numeration="35" content_type="text"> Takahashi, T. and Kawamukai, T.: Phase detection of electrostatic force by AFM with a conductive tip, Ultramicroscopy, 82, 63–68, 2000. </reference>
		<reference numeration="36" content_type="text"> Trochkine, D., Iwasaka, Y., Matsuki, A., Yamada, M., Kim, Y.-S., Nagatani, T., Zhang, D., Shi, G.-Y., and Shen, Z.: Mineral aerosol particles collected in Dunhuang, China, and their comparison with chemically modified particles collected over Japan, J. Geophys. Res., 108, 8642, doi:10.1029/2003JD003268, 2003. </reference>
		<reference numeration="37" content_type="text"> Villarubia, J. S.: Morphological estimation of tip geometry for scanned probe microscopy, Surf. Sci., 321, 287–300, 1994. </reference>
		<reference numeration="38" content_type="text"> Viswanathan, R., Tian, J., and Marr, D. W. M.: Morphology characterization in multicomponent macromolecular systems using scanning probe phase microscopy, Langmuir, 13, 1840–1843, 1997. </reference>
		<reference numeration="39" content_type="text"> Wittmaack, K. and Strigl, M.: Novel approach to identifying supersaturated metastable ambient aerosol particles, Environ. Sci. Technol., 39, 8177–8184, 2005. </reference>
		<reference numeration="40" content_type="text"> Winterholler, B., Hoppe, P., Andreae, M. O., and Foley, S.: Measurement of sulfur isotope ratios in micrometer-sized samples by NanoSIMS, Appl. Surf. Sci., 252, 7128–7131, 2006. </reference>
	</references>
</article>

