Articles | Volume 10, issue 3
https://doi.org/10.5194/amt-10-1061-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-10-1061-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
16 Mar 2017
Research article |
| 16 Mar 2017
Quantitation of 11 alkylamines in atmospheric samples: separating structural isomers by ion chromatography
Bryan K. Place
Department of Chemistry, Memorial University, St. John's, NL, Canada
Department of Earth Sciences, Memorial University, St. John's, NL,
Canada
Aleya T. Quilty
Department of Earth Sciences, Memorial University, St. John's, NL,
Canada
Robert A. Di Lorenzo
Department of Chemistry, Memorial University, St. John's, NL, Canada
Susan E. Ziegler
Department of Earth Sciences, Memorial University, St. John's, NL,
Canada
Department of Earth Sciences, Memorial University, St. John's, NL,
Canada
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Cited
27 citations as recorded by crossref.
- Seasonal variations of low molecular alkyl amines in PM2.5 in a North China Plain industrial city: Importance of secondary formation and combustion emissions X. Yang et al. 10.1016/j.scitotenv.2022.159371
- Kinetics and Products of the Aqueous Phase Oxidation of Triethylamine by OH Y. Tao et al. 10.1021/acsearthspacechem.1c00162
- A Quantitative Method to Measure and Speciate Amines in Ambient Aerosol Samples A. Sullivan et al. 10.3390/atmos11080808
- Enhancing characterization of organic nitrogen components in aerosols and droplets using high-resolution aerosol mass spectrometry X. Ge et al. 10.5194/amt-17-423-2024
- Simultaneous determination of nine atmospheric amines and six inorganic ions by non-suppressed ion chromatography using acetonitrile and 18-crown-6 as eluent additive H. Feng et al. 10.1016/j.chroma.2020.461234
- Gas-to-particle partitioning of atmospheric amines observed at a mountain site in southern China F. Liu et al. 10.1016/j.atmosenv.2018.09.038
- Concentration, size distribution and dry deposition of amines in atmospheric particles of urban Guangzhou, China F. Liu et al. 10.1016/j.atmosenv.2017.10.016
- Composition of Size-Resolved Aged Boreal Fire Aerosols: Brown Carbon, Biomass Burning Tracers, and Reduced Nitrogen R. Di Lorenzo et al. 10.1021/acsearthspacechem.7b00137
- Optimized procedure for the determination of alkylamines in airborne particulate matter of anthropized areas D. Spolaor et al. 10.5194/ar-1-29-2023
- Quantification of Amines in Refinery Process Water via Surface-Enhanced Raman Spectroscopy M. Benhabib et al. 10.1021/acs.energyfuels.2c03636
- New particle formation in the sulfuric acid–dimethylamine–water system: reevaluation of CLOUD chamber measurements and comparison to an aerosol nucleation and growth model A. Kürten et al. 10.5194/acp-18-845-2018
- Characterization of Particle Size Distributions and Water-Soluble Ions in Particulate Matter Measured at a Broiler Farm P. Silva et al. 10.3390/agriculture13071284
- Towards a generic method for ion chromatography/mass spectrometry of low‐molecular‐weight amines in pharmaceutical drug discovery and development Z. Lewis et al. 10.1002/rcm.8680
- Implications for new particle formation in air of the use of monoethanolamine in carbon capture and storage V. Perraud et al. 10.1039/D4CP00316K
- Characterization of organic nitrogen in aerosols at a forest site in the southern Appalachian Mountains X. Chen et al. 10.5194/acp-18-6829-2018
- Emerging investigator series: an instrument to measure and speciate the total reactive nitrogen budget indoors: description and field measurements L. Crilley et al. 10.1039/D2EM00446A
- Amines in boreal forest air at SMEAR II station in Finland M. Hemmilä et al. 10.5194/acp-18-6367-2018
- A new advance in the pollution profile, transformation process, and contribution to aerosol formation and aging of atmospheric amines X. Shen et al. 10.1039/D2EA00167E
- Determination of ammonium and biogenic amines by ion chromatography. A review R. Michalski et al. 10.1016/j.chroma.2021.462319
- Direct Determination of Diethanolamine in High Salinity Dehydrogenation Reaction Solutions by Ion Chromatography (IC) X. Zhang et al. 10.1080/00032719.2021.1916515
- Low contributions of dimethyl sulfide (DMS) chemistry to atmospheric aerosols over the high Arctic Ocean M. Zhang et al. 10.1016/j.atmosenv.2023.120073
- Characterizing Atmospheric Aerosols off the Atlantic Canadian Coast During C-FOG N. Chisholm et al. 10.1007/s10546-021-00673-7
- Suppressor and calibration standard limitations in cation chromatography of ammonium and 10 alkylamines in atmospheric samples L. Salehpoor & T. VandenBoer 10.1039/D3AY01158E
- The Effects of Aminium and Ammonium Cations on the Ice Nucleation Activity of K‐Feldspar L. Chen et al. 10.1029/2023JD039971
- Elevated levels of chloramines and chlorine detected near an indoor sports complex A. Angelucci et al. 10.1039/D2EM00411A
- Toward the improvement of total nitrogen deposition budgets in the United States J. Walker et al. 10.1016/j.scitotenv.2019.07.058
- Chemical composition and sources of amines in PM2.5 in an urban site of PRD, China S. Huang et al. 10.1016/j.envres.2022.113261
27 citations as recorded by crossref.
- Seasonal variations of low molecular alkyl amines in PM2.5 in a North China Plain industrial city: Importance of secondary formation and combustion emissions X. Yang et al. 10.1016/j.scitotenv.2022.159371
- Kinetics and Products of the Aqueous Phase Oxidation of Triethylamine by OH Y. Tao et al. 10.1021/acsearthspacechem.1c00162
- A Quantitative Method to Measure and Speciate Amines in Ambient Aerosol Samples A. Sullivan et al. 10.3390/atmos11080808
- Enhancing characterization of organic nitrogen components in aerosols and droplets using high-resolution aerosol mass spectrometry X. Ge et al. 10.5194/amt-17-423-2024
- Simultaneous determination of nine atmospheric amines and six inorganic ions by non-suppressed ion chromatography using acetonitrile and 18-crown-6 as eluent additive H. Feng et al. 10.1016/j.chroma.2020.461234
- Gas-to-particle partitioning of atmospheric amines observed at a mountain site in southern China F. Liu et al. 10.1016/j.atmosenv.2018.09.038
- Concentration, size distribution and dry deposition of amines in atmospheric particles of urban Guangzhou, China F. Liu et al. 10.1016/j.atmosenv.2017.10.016
- Composition of Size-Resolved Aged Boreal Fire Aerosols: Brown Carbon, Biomass Burning Tracers, and Reduced Nitrogen R. Di Lorenzo et al. 10.1021/acsearthspacechem.7b00137
- Optimized procedure for the determination of alkylamines in airborne particulate matter of anthropized areas D. Spolaor et al. 10.5194/ar-1-29-2023
- Quantification of Amines in Refinery Process Water via Surface-Enhanced Raman Spectroscopy M. Benhabib et al. 10.1021/acs.energyfuels.2c03636
- New particle formation in the sulfuric acid–dimethylamine–water system: reevaluation of CLOUD chamber measurements and comparison to an aerosol nucleation and growth model A. Kürten et al. 10.5194/acp-18-845-2018
- Characterization of Particle Size Distributions and Water-Soluble Ions in Particulate Matter Measured at a Broiler Farm P. Silva et al. 10.3390/agriculture13071284
- Towards a generic method for ion chromatography/mass spectrometry of low‐molecular‐weight amines in pharmaceutical drug discovery and development Z. Lewis et al. 10.1002/rcm.8680
- Implications for new particle formation in air of the use of monoethanolamine in carbon capture and storage V. Perraud et al. 10.1039/D4CP00316K
- Characterization of organic nitrogen in aerosols at a forest site in the southern Appalachian Mountains X. Chen et al. 10.5194/acp-18-6829-2018
- Emerging investigator series: an instrument to measure and speciate the total reactive nitrogen budget indoors: description and field measurements L. Crilley et al. 10.1039/D2EM00446A
- Amines in boreal forest air at SMEAR II station in Finland M. Hemmilä et al. 10.5194/acp-18-6367-2018
- A new advance in the pollution profile, transformation process, and contribution to aerosol formation and aging of atmospheric amines X. Shen et al. 10.1039/D2EA00167E
- Determination of ammonium and biogenic amines by ion chromatography. A review R. Michalski et al. 10.1016/j.chroma.2021.462319
- Direct Determination of Diethanolamine in High Salinity Dehydrogenation Reaction Solutions by Ion Chromatography (IC) X. Zhang et al. 10.1080/00032719.2021.1916515
- Low contributions of dimethyl sulfide (DMS) chemistry to atmospheric aerosols over the high Arctic Ocean M. Zhang et al. 10.1016/j.atmosenv.2023.120073
- Characterizing Atmospheric Aerosols off the Atlantic Canadian Coast During C-FOG N. Chisholm et al. 10.1007/s10546-021-00673-7
- Suppressor and calibration standard limitations in cation chromatography of ammonium and 10 alkylamines in atmospheric samples L. Salehpoor & T. VandenBoer 10.1039/D3AY01158E
- The Effects of Aminium and Ammonium Cations on the Ice Nucleation Activity of K‐Feldspar L. Chen et al. 10.1029/2023JD039971
- Elevated levels of chloramines and chlorine detected near an indoor sports complex A. Angelucci et al. 10.1039/D2EM00411A
- Toward the improvement of total nitrogen deposition budgets in the United States J. Walker et al. 10.1016/j.scitotenv.2019.07.058
- Chemical composition and sources of amines in PM2.5 in an urban site of PRD, China S. Huang et al. 10.1016/j.envres.2022.113261
Discussed (final revised paper)
Latest update: 24 Apr 2024
Short summary
Amines are important drivers in particle formation and growth, which has implications for Earth’s climate. We developed a novel ion chromatographic method for separating and quantifying the 11 most abundant atmospheric alkyl amines, including three sets of structural isomers and two diamines. The detection limits are in the picogram per injection range. We quantified these analytes in two Canadian biomass burning aerosol samples with ammonium ratios of 1 : 2 up to 1000 : 1.
Amines are important drivers in particle formation and growth, which has implications for...
