Atmospheric Measurement Techniques www.atmos-meas-tech.net 1867-1381 1867-8548 2 2 2009 10.5194/amt-2-337-2009 http://www.atmos-meas-tech.net/2/337/2009/ http://www.atmos-meas-tech.net/2/337/2009/amt-2-337-2009.html http://www.atmos-meas-tech.net/2/337/2009/amt-2-337-2009.pdf 337 353 2009-07-21 MIPAS reduced spectral resolution UTLS-1 mode measurements of temperature, O₃, HNO₃, N₂O, H₂O and relative humidity over ice: retrievals and comparison to MLS S. Chauhan swarup.chauhan@imk.fzk.de M. Höpfner G. P. Stiller T. von Clarmann B. Funke N. Glatthor U. Grabowski A. Linden S. Kellmann M. Milz T. Steck H. Fischer L. Froidevaux A. Lambert M. L. Santee M. Schwartz W. G. Read N. J. Livesey Institut für Meteorologie und Klimaforschung, Forschungszentrum Karlsruhe, Karlsruhe, Germany Instituto de Astrofísica de Andalucía CSIC, Granada, Spain Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA now at: Luleå Tekniska Universitet Institutionen för Rymdvetenskap, Kiruna, Sweden now at: Gymnasium, Neckartenzlingen, Germany During several periods since 2005 the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat has performed observations dedicated to the region of the upper troposphere/lower stratosphere (UTLS). For the duration of November/December 2005 global distributions of temperature and several trace gases from MIPAS UTLS-1 mode measurements have been retrieved using the IMK/IAA (Institut für Meteorologie und Klimaforschung/Instituto de Astrofísica de Andalucía) scientific processor. In the UTLS region a vertical resolution of 3 km for temperaure, 3 to 4 km for H₂O, 2.5 to 3 km for O₃, 3.5 km for HNO₃ and 3.5 to 2.5 km for N₂O has been achieved. The retrieved temperature, H₂O, O₃, HNO₃, N₂O, and relative humidity over ice are intercompared with the Microwave Limb Sounder (MLS/Aura) v2.2 data in the pressure range 316 to 0.68 hPa, 316 to 0.68 hPa, 215 to 0.68 hPa, 215 to 3.16 hPa, 100 to 1 hPa and 316 to 10 hPa, respectively. In general, MIPAS and MLS temperatures are biased within ±4 K over the whole pressure and latitude range. Systematic, latitude-independent differences of −2 to −4 K (MIPAS-MLS) at 121 hPa are explained by previously observed biases in the MLS v2.2 temperature retrievals. Temperature differences of −4 K up to 12 K above 10.0 hPa are present both in MIPAS and MLS with respect to ECMWF (European Centre for Medium-Range Weather Forecasts) and are likely due to deficiencies of the ECMWF analysis data. MIPAS and MLS stratospheric volume mixing ratios (vmr) of H₂O are biased within ±1 ppmv, with indication of oscillations between 146 and 26 hPa in the MLS dataset. Tropical upper tropospheric values of relative humidity over ice measured by the two instruments differ by ±20% in the pressure range ~146 to 68 hPa. These differences are mainly caused by the MLS temperature biases. Ozone mixing ratios agree within 0.5 ppmv (10 to 20%) between 68 and 14 hPa. At pressures smaller than 10 hPa, MIPAS O₃ vmr are higher than MLS by an average of 0.5 ppmv (10%). General agreement between MIPAS and MLS HNO₃ is within the range of −1.0 (−10%) to 1.0 ppbv (20%). MIPAS HNO₃ is 1.0 ppbv (10%) higher compared to MLS between 46 hPa and 10 hPa over the Northern Hemisphere. Over the tropics at 31.6 hPa MLS shows a low bias of more than 1 ppbv (>50%). In general, MIPAS and MLS N₂O vmr agree within 20 to 40 ppbv (20 to 40%). 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