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<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques</journal_title>
		<journal_url>www.atmos-meas-tech.net</journal_url>
		<issn>1867-1381</issn>
		<eissn>1867-8548</eissn>
		<volume_number>3</volume_number>
		<issue_number>2</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/amt-3-507-2010</doi>
	<article_url>http://www.atmos-meas-tech.net/3/507/2010/</article_url>
	<abstract_html>http://www.atmos-meas-tech.net/3/507/2010/amt-3-507-2010.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech.net/3/507/2010/amt-3-507-2010.pdf</fulltext_pdf>
	<start_page>507</start_page>
	<end_page>521</end_page>
	<publication_date>2010-04-29</publication_date>
	<article_title content_type="html">&lt;i&gt;&amp;mu;&lt;/i&gt;Dirac: an autonomous instrument for halocarbon measurements</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>B. Gostlow</name>
		</author>
		<author numeration="2" affiliations="1">
			<name>A. D. Robinson</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>N. R. P. Harris</name>
			<email>Neil.Harris@ozone-sec.ch.cam.ac.uk</email>
		</author>
		<author numeration="4" affiliations="1">
			<name>L. M. O&apos;Brien</name>
		</author>
		<author numeration="5" affiliations="2">
			<name>D. E. Oram</name>
		</author>
		<author numeration="6" affiliations="2">
			<name>G. P. Mills</name>
		</author>
		<author numeration="7" affiliations="2">
			<name>H. M. Newton</name>
		</author>
		<author numeration="8" affiliations="3">
			<name>S. E. Yong</name>
		</author>
		<author numeration="9" affiliations="1,4">
			<name>J. A Pyle</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Centre for Atmospheric Science, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK</affiliation>
		<affiliation numeration="2" content_type="html">School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK</affiliation>
		<affiliation numeration="3" content_type="html">Malaysian Meteorological Department, Ketua Stesen GAW Lembah Danum, Malaysia</affiliation>
		<affiliation numeration="4" content_type="html">National Centre for Atmospheric Science, NCAS-Climate, UK</affiliation>
	</affiliations>
	<abstract content_type="html">We describe a new instrument (&lt;i&gt;&amp;mu;&lt;/i&gt;Dirac) capable of measuring halocarbons in the
atmosphere. Portability, power efficiency and autonomy were critical design
requirements and the resulting instrument can be readily deployed unattended
on a range of platforms: long duration balloon, aircraft, ship and
ground-based stations. The instrument is a temperature programmed gas
chromatograph with electron capture detector (GC-ECD). The design
requirements led to &lt;i&gt;&amp;mu;&lt;/i&gt;Dirac being built in-house with several novel features.
It currently measures a range of halocarbons (including short-lived tracers
having biogenic and anthropogenic sources) with measurement precision
relative standard deviations ranging from &amp;plusmn; 1% (CCl&lt;sub&gt;4&lt;/sub&gt;) to &amp;plusmn; 9%
(CH&lt;sub&gt;3&lt;/sub&gt;I). The prototype instrument was first tested in 2005 and
the instrument has been proved in the field on technically challenging
aircraft and ground-based campaigns. Results from an aircraft and a
ground-based deployment are described.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Bassford, M. R., Simmonds, P. G., and Nickless, G.: An Automated System for Near-Real-Time Monitoring of Trace Atmospheric Halocarbons, Anal. Chem., 70(5), 958–965, doi:10.1021/ac970861z, 1998. </reference>
		<reference numeration="2" content_type="text"> Blake, N. J., Blake, D. R., Simpson, I. J., Lopez, J. P., Johnston, N. A. C., Swanson, A. L., Katzenstein, A. S., Meinardi, S., Sive, B. C., Colman, J. J., Atlas, E., Flocke, F., Vay, S. A., Avery, M. A., and Rowland, F. S., Large-scale Latitudinal and Vertical Distributions of NMHCs and Selected Halocarbons in the Troposphere over the Pacific Ocean during the March–April 1999 Pacific Exploratory Mission (PEM-Tropics B), J. Geophys. Res., 106(D23), 32627–32644, 2001. </reference>
		<reference numeration="3" content_type="text"> Butler, J. H., King, D. B., Lobert, J. M., Montzka, S. A., Yvon-Lewis, S. A., Hall, B. D., Warwick, N. J., Mondeel, D. J., Aydin, M., and Elkins, J. W.: Oceanic distributions and emissions of short-lived halocarbons, Global Biogeochem. Cycles., 21, GB1023, doi:10.1029/2006GB002732, 2007. </reference>
		<reference numeration="4" content_type="text"> Class, Th., Kohnle, R., and Ballschmiter K.: Chemistry of organic traces in air VII: Bromo- and bromochloromethanes in air over the Atlantic Ocean, Chemosphere, 15, 4, 429–436, 1986. </reference>
		<reference numeration="5" content_type="text"> Colman, J. J., Swanson, A. L., Meinardi, S., Sive, B. C., Blake, D. R., and Rowland, F. S.: Description of the Analysis of a Wide Range of Volatile Organic Compounds in Whole Air Samples Collected during PEM-Tropics A and B, Anal. Chem., 73, 3723–3731, 2001. </reference>
		<reference numeration="6" content_type="text"> Danis, F., Harris, N. R. P., Taylor, W. H., McIntyre, J. D., Simmonds, P. G., and Pyle, J. A.: DESCARTES: A novel lightweight balloon-borne instrument for measurement of Halocarbons, Review of Scientific Instruments, 70, 271–280, 2000. </reference>
		<reference numeration="7" content_type="text"> Hall, B. D., Elkins, J. W., Butler, J. H., Montzka, S. A., Thompson, T. M., Del Negro, L., Dutton, G. S., Hurst, D. F., King, D. B., Kline, E. S., Lock, L., Mactaggart, D., Mondeel, D., Moore, F. L., Nance, J. D., Ray, E. A., and Romashkin, P. A.: Climate Monitoring and Diagnostics Laboratory Summary Report No 25, 1998–1999, edited by: Schnell, R. C., King, D. B., and Rosson, R. M., U.S. Department of Commerce, 154~pp., 2001. </reference>
		<reference numeration="8" content_type="text"> Lovelock, J. E. and Lipsky S. R.: Electron Affinity Spectroscopy – A New Method for the Identification of Functional Groups in Chemical Compounds Separated by Gas Chromatography, J. Am. Chem. Soc., 82(2), 431–433, 1960. </reference>
		<reference numeration="9" content_type="text"> Lovelock, J. E.: Atmospheric Fluorine Compounds as Indicators of Air Movements, Nature, 230, 379, 1971. </reference>
		<reference numeration="10" content_type="text"> Lovelock, J. E., Maggs, R. J., and Wade, R. J.: Halogenated Hydrocarbons in and over the Atlantic, Nature, 241, 194–196, 1973. </reference>
		<reference numeration="11" content_type="text"> Miller, B. R., Weiss, R. F., Salameh, P. K., Tanhua, T., Greally, B. R., Mühle, J., and Simmonds, P. G.: Medusa: A Sample Preconcentration and GC/MS Detector System for in Situ Measurements of Atmospheric Trace Halocarbons, Hydrocarbons, and Sulfur Compounds, Anal. Chem., 80, 1536–1545, doi:10.1021/ac702084k, 2008. </reference>
		<reference numeration="12" content_type="text"> Montzka, S. A., Butler, J. H., Elkins, J. W., Thompson, T. M., Clarke, A. D., and Lock, L. T.: Present and future trends in the atmospheric burden of ozone-depleting halogens, Nature, 398, 690–694, 1999. </reference>
		<reference numeration="13" content_type="text"> Morris, P. J. T. and Ettre, L. S., The Saga of the Electron Capture Detector, LC/GC-Europe, 20, 473–479, 2007. </reference>
		<reference numeration="14" content_type="text"> O&apos;Brien, L. M., Harris, N. R. P., Robinson, A. D., Gostlow, B., Warwick, N., Yang, X., and Pyle, J. A.: Bromocarbons in the tropical marine boundary layer at the Cape Verde Observatory - measurements and modelling, Atmos. Chem. Phys. Discuss., 9, 4335–4379, 2009. </reference>
		<reference numeration="15" content_type="text"> Penkett, S. A., Jones, B. M. R., Rycroft, M. J., and Simmons, D. A.: An interhemispheric comparison of the concentrations of bromine compounds in the atmosphere, Nature, 318, 550–553, doi:10.1038/318550a0, 1985. </reference>
		<reference numeration="16" content_type="text"> Pommereau, J.-P. and Hauchecorne, A.: A new atmospheric vehicle: The Infra-Red Montgolfier, in Scientific Ballooning, pp 55–58, Pergamon, New York, 1979. </reference>
		<reference numeration="17" content_type="text"> Pommereau, J.-P., Garnier, A., Knudsen, B. M., Letrenne, G., Durand, M., Nunes-Pinharanda, M., Denis, L., Vial, F., Hertzog, A., and Cairo, F., Accuracy of analyzed stratospheric temperatures in the winter Arctic vortex from infrared Montgolfier long-duration balloon flights 1. Measurements, J. Geophys. Res., 107, 8260, doi:10.1029/2001JD001379, 2002. </reference>
		<reference numeration="18" content_type="text"> Prinn, R. G., Weiss, R. F., Fraser, P. J., Simmonds, P. G., Cunnold, D. M., Alyea, F. N., O&apos;Doherty, S., Salameh, P., Miller, B. R., Huang, J., Wang, R. H. J., Hartley, D. E., Harth, C., Steele, L. P., Sturrock, G., Midgley, P. M., and McCulloch, A. J., A history of chemically and radiatively important gases in air deduced from ALE/GAGE/AGAGE, J. Geophys. Res., 105(D14), 17751–17792, 2000. </reference>
		<reference numeration="19" content_type="text"> Proffitt, M. H., Margitan, J. J., Kelly, K. K., Lowenstein, M., Podolske, J. R., and Chan, K.: Ozone loss in the Arctic polar vortex inferred from high-altitude aircraft measurements, Nature, 347, 31–36, 1990. </reference>
		<reference numeration="20" content_type="text"> Proffitt, M. H., Aikin, K., Margitan, J. J., Lowenstein, M., Podolske, J. R., Weaver, A., Chan, K. R., Fast, H., and Elkins, J. W.: Ozone loss inside the northern polar vortex during the 1991–1992 winter, Science, 261, 1150–1154, 1993. </reference>
		<reference numeration="21" content_type="text"> Ray, E. A., Moore, F. L., Elkins, J. W., Dutton, G. S., Fahey, D. W., Vömel, H., Oltmans, S. J., and Rosenlof, K. H., Transport into the Northern Hemisphere lowermost stratosphere revealed by in situ tracer measurements, J. Geophys. Res., 104, 26565–26580, 1999. </reference>
		<reference numeration="22" content_type="text"> Ray, E. A., Moore, F. L., Elkins, J. W., Hurst, D. F., Romashkin, P. A., Dutton, G. S., and Fahey, D. W.: Descent and mixing in the 1999–2000 northern polar vortex inferred from in situ tracer measurements, J. Geophys. Res., 107(D20), 8285, doi:10.1029/2001JD000961, 2002. </reference>
		<reference numeration="23" content_type="text"> Robinson, A. D., McIntyre, J., Harris, N. R. P., Pyle, J. A., Simmonds, P. G., and Danis, F.: A lightweight balloon-borne gas chromatograph for in-situ measurements of atmospheric halocarbons, Rev. Sci. Instru., 71, 4553–4560, 2000. </reference>
		<reference numeration="24" content_type="text"> Robinson, A. D., Millard, G. A., Danis, F., Guirlet, M., Harris, N. R. P., Lee, A. M., McIntyre, J. D., Pyle, J. A., Arvelius, J., Dagnesjo, S., Kirkwood, S., Nilsson, H., Toohey, D. W., Deshler, T., Goutail, F., Pommereau, J.-P., Elkins, J. W., Moore, F., Ray, E., Schmidt, U., Engel, A., and Müller, M.: Ozone loss derived from balloon-borne tracer measurements in the 1999/2000 Arctic winter, Atmos. Chem. Phys., 5, 1423–1436, 2005. </reference>
		<reference numeration="25" content_type="text"> Ross, D. E. M., Pyle, J. A., Harris, N. R. P., McIntyre, J. D., Millard, G. A., Robinson, A. D., and Busen, R.: Investigation of Arctic ozone depletion sampled over midlatitudes during the Egrett campaign of spring/summer 2000, Atmos. Chem. Phys., 4, 1407–1417, 2004. </reference>
		<reference numeration="26" content_type="text"> Schmidt, U., Bauer, R., Engel, A., Borchers, R., and Lee, J., The variation of available chlorine Cly in the arctic polar vortex during EASOE, Geophys. Res. Lett., 21, 1215–1218, 1994. </reference>
		<reference numeration="27" content_type="text"> Tienpont, B., David, F., Witdouck, W., and Sandra, P., Development of a miniature gas chromatograph (μCAD) with sample Enrichment, Programmed Temperature GC and Plasma Emission Detection, LC/GC Europe, 22, 112–124, 2009. </reference>
		<reference numeration="28" content_type="text"> Urban, J., Lautie, N., Le Flochmoen, E., Jimenez, C., Eriksson, P., de La Noe, J., Dupuy, E., El Amraoui, L., Frisk, U., Jegou, F., Murtagh, D., Olberg, M., Ricaud, P., Camy-Peyret, C., Dufour, G., Payan, S., Huret, N., Pirre, M., Robinson, A. D., Harris, N. R. P., Bremer, H., Kleinbohl, A., Kullmann, K., Kunzi, K., Kuttippurath, J., Ejiri, M., Nakajima, H., Sasano, Y., Sugita, T., Yokota, T., Piccolo, C., Raspollini, P., and. Ridolfi, M.: Odin/SMR Limb Observations of Stratospheric Trace Gases: Validation of N&lt;sub&gt;2&lt;/sub&gt;O, J. Geophys. Res., 110, D09301, doi:10.1029/2004JD005394, 2005. </reference>
		<reference numeration="29" content_type="text"> Volk, C. M. Elkins, J. W., Fahey, D. W., Salawitch, R. J., Dutton, G. S., Gilligan, J. M., Proffitt, M. H., Loewenstein, M., Podolske, J. R., Minschwaner, K., Margitan, J. J., and Chan, K. R., Quantifying Transport Between the Tropical and Mid-Latitude Lower Stratosphere, Science, 272, 1763–1768, doi:10.1126/science.272.5269.1763, 1996. </reference>
		<reference numeration="30" content_type="text"> Worton, D.R., Mills, G. P., Oram, D. E., and Sturges, W. T.: Gas chromatography negative ion chemical ionisation mass spectrometry: Application to the detection of alkyl nitrates and halocarbons in the atmosphere, J. Chromatogr. A, 1201, 112–119, doi:10.1016/j.chroma.2008.06.019, 2008. </reference>
	</references>
</article>

