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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union

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Atmos. Meas. Tech., 5, 1349-1357, 2012
http://www.atmos-meas-tech.net/5/1349/2012/
doi:10.5194/amt-5-1349-2012
© Author(s) 2012. This work is distributed
under the Creative Commons Attribution 3.0 License.
Research article
14 Jun 2012
A simple empirical model estimating atmospheric CO2 background concentrations
M. Reuter1, M. Buchwitz1, O. Schneising1, F. Hase2, J. Heymann1, S. Guerlet3, A. J. Cogan4, H. Bovensmann1, and J. P. Burrows1 1University of Bremen, Institute of Environmental Physics, Bremen, Germany
2Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, Karlsruhe, Germany
3Netherlands Institute for Space Research (SRON), Utrecht, The Netherlands
4University of Leicester, Department of Physics and Astronomy, Leicester, UK
Abstract. A simple empirical CO2 model (SECM) is presented to estimate column-average dry-air mole fractions of atmospheric CO2 (XCO2) as well as mixing ratio profiles. SECM is based on a simple equation depending on 17 empirical parameters, latitude, and date. The empirical parameters have been determined by least squares fitting to NOAA's (National Oceanic and Atmospheric Administration) assimilation system CarbonTracker version 2010 (CT2010). Comparisons with TCCON (total carbon column observing network) FTS (Fourier transform spectrometer) measurements show that SECM XCO2 agrees quite well with reality. The synthetic XCO2 values have a standard error of 1.39 ppm and systematic station-to-station biases of 0.46 ppm. Typical column averaging kernels of the TCCON FTS, a SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric CHartographY), and two GOSAT (Greenhouse gases Observing SATellite) XCO2 retrieval algorithms have been used to assess the smoothing error introduced by using SECM profiles instead of CT2010 profiles as a priori. The additional smoothing error amounts to 0.17 ppm for a typical SCIAMACHY averaging kernel and is most times much smaller for the other instruments (e.g. 0.05 ppm for a typical TCCON FTS averaging kernel). Therefore, SECM is well suited to provide a priori information for state-of-the-art ground-based (FTS) and satellite-based (GOSAT, SCIAMACHY) XCO2 retrievals. Other potential applications are: (i) near real-time processing systems (that cannot make use of models like CT2010 operated in delayed mode), (ii) "CO2 proxy" methods for XCH4 retrievals (as correction for the XCO2 background), and (iii) observing system simulation experiments especially for future satellite missions.

Citation: Reuter, M., Buchwitz, M., Schneising, O., Hase, F., Heymann, J., Guerlet, S., Cogan, A. J., Bovensmann, H., and Burrows, J. P.: A simple empirical model estimating atmospheric CO2 background concentrations, Atmos. Meas. Tech., 5, 1349-1357, doi:10.5194/amt-5-1349-2012, 2012.
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