1Institute for Atmospheric and Environmental Sciences, Goethe
University of Frankfurt, 60438 Frankfurt am Main, Germany
2Laboratory of Atmospheric Chemistry, Paul-Scherrer-Institute, 5232
3Institute for Atmospheric and Climate Science, ETH Zürich, 8092
4Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki,
Received: 30 Sep 2015 – Discussion started: 17 Dec 2015
Abstract. Amines are potentially important for atmospheric new particle formation, but their concentrations are usually low with typical mixing ratios in the pptv range or even smaller. Therefore, the demand for highly sensitive gas-phase amine measurements has emerged in the last several years. Nitrate chemical ionization mass spectrometry (CIMS) is routinely used for the measurement of gas-phase sulfuric acid in the sub-pptv range. Furthermore, extremely low volatile organic compounds (ELVOCs) can be detected with a nitrate CIMS. In this study we demonstrate that a nitrate CIMS can also be used for the sensitive measurement of dimethylamine (DMA, (CH3)2NH) using the NO3−•(HNO3)1 − 2• (DMA) cluster ion signal. Calibration measurements were made at the CLOUD chamber during two different measurement campaigns. Good linearity between 0 and ∼ 120 pptv of DMA as well as a sub-pptv detection limit of 0.7 pptv for a 10 min integration time are demonstrated at 278 K and 38 % RH.
Revised: 15 Apr 2016 – Accepted: 18 Apr 2016 – Published: 13 May 2016
Simon, M., Heinritzi, M., Herzog, S., Leiminger, M., Bianchi, F., Praplan, A., Dommen, J., Curtius, J., and Kürten, A.: Detection of dimethylamine in the low pptv range using nitrate chemical ionization atmospheric pressure interface time-of-flight (CI-APi-TOF) mass spectrometry, Atmos. Meas. Tech., 9, 2135-2145, doi:10.5194/amt-9-2135-2016, 2016.