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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 10, issue 6
Atmos. Meas. Tech., 10, 2283-2298, 2017
https://doi.org/10.5194/amt-10-2283-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 10, 2283-2298, 2017
https://doi.org/10.5194/amt-10-2283-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 22 Jun 2017

Research article | 22 Jun 2017

Controlled nitric oxide production via O(1D)  + N2O reactions for use in oxidation flow reactor studies

Andrew Lambe et al.
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This work enables the study of NOx-influenced secondary organic aerosol formation chemistry in oxidation flow reactors to an extent that was not previously possible. The method uses reactions of exited oxygen O(1D) radicals (formed from ozone photolysis at 254 nm or nitrous oxide photolysis at 185 nm) with nitrous oxide (N2O) to produce NO. We demonstrate proof of concept using chemical ionization mass spectrometer measurements to detect gas-phase oxidation products of isoprene and α-pinene.
This work enables the study of NOx-influenced secondary organic aerosol formation chemistry in...
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