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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 10, issue 7 | Copyright

Special issue: Twenty-five years of operations of the Network for the Detection...

Atmos. Meas. Tech., 10, 2425-2434, 2017
https://doi.org/10.5194/amt-10-2425-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 06 Jul 2017

Research article | 06 Jul 2017

Background CO2 levels and error analysis from ground-based solar absorption IR measurements in central Mexico

Jorge L. Baylon1, Wolfgang Stremme1, Michel Grutter1, Frank Hase2, and Thomas Blumenstock2 Jorge L. Baylon et al.
  • 1Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico City, Mexico
  • 2Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany

Abstract. In this investigation we analyze two common optical configurations to retrieve CO2 total column amounts from solar absorption infrared spectra. The noise errors using either a KBr or a CaF2 beam splitter, a main component of a Fourier transform infrared spectrometer (FTIR), are quantified in order to assess the relative precisions of the measurements. The configuration using a CaF2 beam splitter, as deployed by the instruments which contribute to the Total Carbon Column Observing Network (TCCON), shows a slightly better precision. However, we show that the precisions in XCO2 ( = 0.2095 ⋅ Total Column CO2Total Column O2) retrieved from  > 96% of the spectra measured with a KBr beam splitter fall well below 0.2%. A bias in XCO2 (KBrCaF2) of +0.56±0.25ppm was found when using an independent data set as reference. This value, which corresponds to +0.14±0.064%, is slightly larger than the mean precisions obtained. A 3-year XCO2 time series from FTIR measurements at the high-altitude site of Altzomoni in central Mexico presents clear annual and diurnal cycles, and a trend of +2.2ppmyr−1 could be determined.

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In this investigation we analyze two common optical configurations to retrieve CO2 total column amounts from solar absorption infrared spectra. The noise errors using either a KBr or CaF2 beam splitter, a main component of a Fourier transform infrared spectrometer, are quantified in order to assess the relative precisions of the measurements. A 3-year XCO2 time series at the high-altitude site of Altzomoni in central Mexico presents clear annual and diurnal cycles and a trend of +2.2 ppm yr-1.
In this investigation we analyze two common optical configurations to retrieve CO2 total column...
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