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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 10, issue 7
Atmos. Meas. Tech., 10, 2669–2685, 2017
https://doi.org/10.5194/amt-10-2669-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 10, 2669–2685, 2017
https://doi.org/10.5194/amt-10-2669-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 26 Jul 2017

Research article | 26 Jul 2017

Abundances of isotopologues and calibration of CO2 greenhouse gas measurements

Pieter P. Tans et al.
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Andres, R. J., Marland, G., Boden, T., and Bischof, S.: Carbon dioxide emissions from fossil fuel consumption and cement manufacture, 1751–1991, and an estimate of their isotopic compostition and latitudinal distribution, in: The Carbon Cycle, edited by: Wigley, T. M. L. and Schimel, D. S., Cambridge University Press, Cambridge, 53–62, 2000.
Allison, C. E., Francey, R. J., and Meijer, A. J.: Recommendations for the reporting of stable isotope measurements of carbon and oxygen in CO2 gas, reference and intercomparison materials for stable isotopes of light elements, IAEA-TECDOC-825, Vienna, 155–162, 1995.
Assonov, S. S. and Brenninkmeijer, C. A. M.: A redetermination of absolute values for 17RVPDB − CO2 and 17RVSMOW, Rapid Commun. Mass Spectrom., 17, 1017–1029, 2003.
Baer, D. S., Paul, J. B., Gupta, J. B., and O'Keefe, A.: Sensitive absorption measurements in the near-infrared region using off-axis integrated-cavity-output spectroscopy, Appl. Phys. B-Laser. O., 75, 261–265, https://doi.org/10.1007/s00340-002-0971-z, 2002.
Baertschi, P.: Absolute 18O content of Standard Mean Ocean Water, Earth Planet. Sc. Lett., 31, 341–344, 1976.
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We describe a new CO2 calibration system for the Central Calibration Laboratory of the World Meteorological Organization Global Atmosphere Watch program. The system uses two laser spectroscopic instruments to measure the three major CO2 isotopologues individually. We account for isotopic differences between standards in the calibration hierarchy when assigning CO2 mole fraction, eliminating bias due to variations in the isotopic composition.
We describe a new CO2 calibration system for the Central Calibration Laboratory of the World...
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