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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 10, issue 1
Atmos. Meas. Tech., 10, 291–313, 2017
https://doi.org/10.5194/amt-10-291-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 10, 291–313, 2017
https://doi.org/10.5194/amt-10-291-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 26 Jan 2017

Research article | 26 Jan 2017

An improved, automated whole air sampler and gas chromatography mass spectrometry analysis system for volatile organic compounds in the atmosphere

Brian M. Lerner et al.

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Cited articles

Apel, E. C., Calvert, J. G., Gilpin, T. M., Fehsenfeld, F., and Lonneman, W. A.: Nonmethane Hydrocarbon Intercomparison Experiment (NOMHICE): Task 4, ambient air, J. Geophys. Res.-Atmos., 108, 4300, https://doi.org/10.1029/2002JD002936, 2003a.
Apel, E. C., Hills, A. J., Lueb, R., Zindel, S., Eisele, S., and Riemer, D. D.: A fast-GC/MS system to measure C-2 to C-4 carbonyls and methanol aboard aircraft, J. Geophys. Res.-Atmos., 108, https://doi.org/10.1029/2002jd003199, 2003b.
Blake, D. R., Smith, T. W., Chen, T. Y., Whipple, W. J., and Rowland, F. S.: Effects of biomass burning on summertime nonmethane hydrocarbon concentrations in the Canadian wetlands, J. Geophys. Res.-Atmos., 99, 1699–1719, https://doi.org/10.1029/93jd02598, 1994.
Brown, R. H. and Purnell, C. J.: Collection and analysis of trace organic vapour pollutants in ambient atmospheres, J. Chromatogr. A, 178, 79–90, https://doi.org/10.1016/S0021-9673(00)89698-3, 1979.
Colman, J. J., Swanson, A. L., Meinardi, S., Sive, B. C., Blake, D. R., and Rowland, F. S.: Description of the analysis of a wide range of volatile organic compounds in whole air samples collected during PEM-Tropics A and B, Anal. Chem., 73, 3723–3731, https://doi.org/10.1021/ac010027g, 2001.
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Short summary
Whole air sampling followed by analysis by gas chromatography is a common technique for characterization of trace volatile organic compounds in the atmosphere. We describe a new automated gas chromatograph–mass spectrograph which uses a Stirling cooler for sample preconcentration at −165 °C without the need for a cryogen such as liquid nitrogen. We also discuss potential sources of artifacts from our electropolished stainless steel sampling system and present results from two field campaigns.
Whole air sampling followed by analysis by gas chromatography is a common technique for...
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