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Volume 10, issue 12 | Copyright
Atmos. Meas. Tech., 10, 4687-4696, 2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 04 Dec 2017

Research article | 04 Dec 2017

Effects of gas–wall partitioning in Teflon tubing and instrumentation on time-resolved measurements of gas-phase organic compounds

Demetrios Pagonis et al.
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Cited articles
Bian, Q., May, A. A., Kreidenweis, S. M., and Pierce, J. R.: Investigation of particle and vapor wall-loss effects on controlled wood-smoke smog-chamber experiments, Atmos. Chem. Phys., 15, 11027–11045,, 2015.
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de Gouw, J. and Warneke, C.: Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrom. Rev., 26, 223–257,, 2007.
Donahue, N. M., Robinson, A. L., Stanier, C. O., and Pandis, S. N.: Coupled partitioning, dilution, and chemical aging of semivolatile organics, Environ. Sci. Technol., 40, 2635–2643,, 2006.
Guiochon, G., Felinger, A., Shirazi, D. G., and Katti, A. M.: Fundamentals of Preparative and Nonlinear Chromatography, 1st edn., Elsevier Inc, San Diego, CA, USA, 2006.
Publications Copernicus
Short summary
Laboratory studies were conducted to investigate gas-wall partitioning of atmospheric organic compounds in Teflon tubing and inside an instrument used to monitor concentrations. Rapid partitioning caused time delays in instrument response that vary with tubing length and diameter, flow rate, and compound volatility. Tubing delay times of seconds to hours were described using a model that also included effects of instrument surfaces. The results can enable better design of air sampling systems.
Laboratory studies were conducted to investigate gas-wall partitioning of atmospheric organic...