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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 10, issue 12 | Copyright
Atmos. Meas. Tech., 10, 4819-4831, 2017
https://doi.org/10.5194/amt-10-4819-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 12 Dec 2017

Research article | 12 Dec 2017

The tilt effect in DOAS observations

Johannes Lampel1,a, Yang Wang1,2, Andreas Hilboll3,4, Steffen Beirle1, Holger Sihler1,5, Janis Puķīte1, Ulrich Platt1,5, and Thomas Wagner1 Johannes Lampel et al.
  • 1Satellite Remote Sensing Group, Max Planck Institute for Chemistry, Mainz, Germany
  • 2Anhui Institute of Optics and Fine Mechanics, Chinese Academy Sciences, Hefei, China
  • 3Institute of Environmental Physics (IUP), University of Bremen, Bremen, Germany
  • 4Center for Marine Environmental Sciences (MARUM), University of Bremen, Bremen, Germany
  • 5Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
  • anow at: Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany

Abstract. Experience of differential atmospheric absorption spectroscopy (DOAS) shows that a spectral shift between measurement spectra and reference spectra is frequently required in order to achieve optimal fit results, while the straightforward calculation of the optical density proves inferior. The shift is often attributed to temporal instabilities of the instrument but implicitly solved the problem of the tilt effect discussed/explained in this paper.

Spectral positions of Fraunhofer and molecular absorption lines are systematically shifted for different measurement geometries due to an overall slope – or tilt – of the intensity spectrum. The phenomenon has become known as the tilt effect for limb satellite observations, where it is corrected for in a first-order approximation, whereas the remaining community is less aware of its cause and consequences.

It is caused by the measurement process, because atmospheric absorption and convolution in the spectrometer do not commute. Highly resolved spectral structures in the spectrum will first be modified by absorption and scattering processes in the atmosphere before they are recorded with a spectrometer, which convolves them with a specific instrument function. In the DOAS spectral evaluation process, however, the polynomial (or other function used for this purpose) accounting for broadband absorption is applied after the convolution is performed.

In this paper, we derive that changing the order of the two modifications of the spectra leads to different results. Assuming typical geometries for the observations of scattered sunlight and a spectral resolution of 0.6nm, this effect can be interpreted as a spectral shift of up to 1.5pm, which is confirmed in the actual analysis of the ground-based measurements of scattered sunlight as well as in numerical radiative transfer simulations. If no spectral shift is allowed by the fitting routine, residual structures of up to 2.5×10−3 peak-to-peak are observed. Thus, this effect needs to be considered for DOAS applications aiming at an rms of the residual of 10−3 and below.

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Experience of differential atmospheric absorption spectroscopy (DOAS) shows that a spectral shift between measurement and reference spectrum is frequently required in order to achieve optimal fit results. The shift is often attributed to temporal instabilities of the instrument but implicitly solved the problem of the tilt effect discussed in this paper. The tilt effect results from the finite resolution of the measurements and amounts to 2 pm for the example data set.
Experience of differential atmospheric absorption spectroscopy (DOAS) shows that a spectral...
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