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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union

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Atmos. Meas. Tech., 10, 4877-4894, 2017
https://doi.org/10.5194/amt-10-4877-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
Research article
14 Dec 2017
An intercomparison of HO2 measurements by fluorescence assay by gas expansion and cavity ring-down spectroscopy within HIRAC (Highly Instrumented Reactor for Atmospheric Chemistry)
Lavinia Onel et al.
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Interactive discussionStatus: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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RC1: 'Review on “An intercomparison of HO2 measurements by Fluorescence Assay by Gas Expansion and Cavity Ring–Down Spectroscopy within HIRAC” by L.Onel et al.', Anonymous Referee #1, 05 Sep 2017 Printer-friendly Version 
AC1: 'Author response to referee 1', Lavinia Onel, 24 Oct 2017 Printer-friendly Version Supplement 
 
RC2: 'Review of Onel et al.', Anonymous Referee #2, 08 Sep 2017 Printer-friendly Version 
AC2: 'Author response to referee 2', Lavinia Onel, 24 Oct 2017 Printer-friendly Version Supplement 
Peer review completion
AR: Author's response | RR: Referee report | ED: Editor decision
AR by Lavinia Onel on behalf of the Authors (26 Oct 2017)  Author's response  Manuscript
ED: Publish as is (02 Nov 2017) by Hendrik Fuchs
CC BY 4.0
Publications Copernicus
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Short summary
Hydroperoxy (HO2) radicals are key intermediates participating in a rapid chemical cycling at the centre of the tropospheric oxidation. Fluorescence assay by gas expansion (FAGE) technique is the most commonly used for the HO2 measurements in the atmosphere. However, FAGE is an indirect technique, requiring calibration. This work finds a good agreement between the indirect FAGE method and the direct cavity ring-down spectroscopy method and hence validates FAGE and the FAGE calibration method.
Hydroperoxy (HO2) radicals are key intermediates participating in a rapid chemical cycling at...
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