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Volume 10, issue 12 | Copyright
Atmos. Meas. Tech., 10, 4877-4894, 2017
https://doi.org/10.5194/amt-10-4877-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 14 Dec 2017

Research article | 14 Dec 2017

An intercomparison of HO2 measurements by fluorescence assay by gas expansion and cavity ring-down spectroscopy within HIRAC (Highly Instrumented Reactor for Atmospheric Chemistry)

Lavinia Onel et al.
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Short summary
Hydroperoxy (HO2) radicals are key intermediates participating in a rapid chemical cycling at the centre of the tropospheric oxidation. Fluorescence assay by gas expansion (FAGE) technique is the most commonly used for the HO2 measurements in the atmosphere. However, FAGE is an indirect technique, requiring calibration. This work finds a good agreement between the indirect FAGE method and the direct cavity ring-down spectroscopy method and hence validates FAGE and the FAGE calibration method.
Hydroperoxy (HO2) radicals are key intermediates participating in a rapid chemical cycling at...
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