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AMT | Articles | Volume 11, issue 1
Atmos. Meas. Tech., 11, 1–16, 2018
https://doi.org/10.5194/amt-11-1-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Meas. Tech., 11, 1–16, 2018
https://doi.org/10.5194/amt-11-1-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 03 Jan 2018

Research article | 03 Jan 2018

Measurements of a potential interference with laser-induced fluorescence measurements of ambient OH from the ozonolysis of biogenic alkenes

Pamela Rickly and Philip S. Stevens
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Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-726,https://doi.org/10.5194/acp-2019-726, 2019
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Cited articles  
Aschmann, S. M., Arey, J., and Atkinson, R.: OH radical formation from the gas-phase reactions of O3 with a series of terpenes, Atmos. Environ., 36, 4347–4355, 2002. 
Atkinson, R.: Gas Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes, J. Phys. Chem. Ref. Data, 26, 215–290, 1997. 
Atkinson, R., Aschmann, S. M., Arey, J., and Shorees, B.: Formation of OH Radicals in the Gas-Phase Reactions of O3 with a Series of Terpenes, J. Geophys. Res.-Atmos., 97, 6065–6073, 1992. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006. 
Chao, W., Hsieh, J.-T., Chang, C.-H., and Lin, J. J.-M.: Direct kinetic measurement of the reaction of the simplest Criegee intermediate with water vapor, Science, 347, 751–754, 2015. 
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The hydroxyl radical is the primary atmospheric oxidant in the atmosphere, and measurements of its concentration provide a rigorous test of our understanding of atmospheric chemistry. This paper presents measurements of a potential interference with measurements of OH using laser-induced fluorescence techniques, which may contribute to measurements of OH in forested environments. The results may help to explain discrepancies between measurements and model predictions in these environments.
The hydroxyl radical is the primary atmospheric oxidant in the atmosphere, and measurements of...
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