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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 11, issue 4
Atmos. Meas. Tech., 11, 1851–1881, 2018
https://doi.org/10.5194/amt-11-1851-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Meas. Tech., 11, 1851–1881, 2018
https://doi.org/10.5194/amt-11-1851-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 04 Apr 2018

Research article | 04 Apr 2018

An ion-neutral model to investigate chemical ionization mass spectrometry analysis of atmospheric molecules – application to a mixed reagent ion system for hydroperoxides and organic acids

Brian G. Heikes et al.

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Short summary
A CIMS utilizing a multi-species negative ion chemistry was designed to measure peroxides and organic acids throughout the troposphere from an aircraft. Prior CIMS used a single reagent ion, and the multi-ion approach has the potential to be a significant step forward, although one with analytical risk. Here, a chemical kinetics numerical model is presented which simulates its past water vapor and pressure dependence, providing a test bed to characterize its use in future environments.
A CIMS utilizing a multi-species negative ion chemistry was designed to measure peroxides and...
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