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Volume 11, issue 7 | Copyright
Atmos. Meas. Tech., 11, 4033-4058, 2018
https://doi.org/10.5194/amt-11-4033-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 11 Jul 2018

Research article | 11 Jul 2018

Improved slant column density retrieval of nitrogen dioxide and formaldehyde for OMI and GOME-2A from QA4ECV: intercomparison, uncertainty characterisation, and trends

Marina Zara1, K. Folkert Boersma1,2, Isabelle De Smedt3, Andreas Richter4, Enno Peters4, Jos H. G. M. van Geffen1, Steffen Beirle5, Thomas Wagner5, Michel Van Roozendael3, Sergey Marchenko6, Lok N. Lamsal6, and Henk J. Eskes1 Marina Zara et al.
  • 1Royal Netherlands Meteorological Institute, KNMI, De Bilt, the Netherlands
  • 2Wageningen University, WUR, Meteorology and Air Quality Group, Wageningen, the Netherlands
  • 3Institut royal d'Aéronomie Spatiale de Belgique, BIRA-IASB, Brussels, Belgium
  • 4Institut für Umweltphysik, IUP, Bremen, Germany
  • 5Max-Planck-Institut für Chemie, MPI, Mainz, Germany
  • 6Goddard Space Flight Center, NASA, Greenbelt, USA

Abstract. Nitrogen dioxide (NO2) and formaldehyde (HCHO) column data from satellite instruments are used for air quality and climate studies. Both NO2 and HCHO have been identified as precursors to the ozone (O3) and aerosol essential climate variables, and it is essential to quantify and characterise their uncertainties. Here we present an intercomparison of NO2 and HCHO slant column density (SCD) retrievals from four different research groups (BIRA-IASB, IUP Bremen, and KNMI as part of the Quality Assurance for Essential Climate Variables (QA4ECV) project consortium, and NASA) and from the OMI and GOME-2A instruments. Our evaluation is motivated by recent improvements in differential optical absorption spectroscopy (DOAS) fitting techniques and by the desire to provide a fully traceable uncertainty budget for the climate data record generated within QA4ECV. The improved NO2 and HCHO SCD values are in close agreement but with substantial differences in the reported uncertainties between groups and instruments. To check the DOAS uncertainties, we use an independent estimate based on the spatial variability of the SCDs within a remote region. For NO2, we find the smallest uncertainties from the new QA4ECV retrieval (0.8 × 1015molec.cm−2 for both instruments over their mission lifetimes). Relative to earlier approaches, the QA4ECV NO2 retrieval shows better agreement between DOAS and statistical uncertainty estimates, suggesting that the improved QA4ECV NO2 retrieval has reduced but not altogether eliminated systematic errors in the fitting approach. For HCHO, we reach similar conclusions (QA4ECV uncertainties of 8–12 × 1015molec.cm−2), but the closeness between the DOAS and statistical uncertainty estimates suggests that HCHO uncertainties are indeed dominated by random noise from the satellite's level 1 data. We find that SCD uncertainties are smallest for high top-of-atmosphere reflectance levels with high measurement signal-to-noise ratios. From 2005 to 2015, OMI NO2 SCD uncertainties increase by 1–2%year−1, which is related to detector degradation and stripes, but OMI HCHO SCD uncertainties are remarkably stable (increase  < 1%year−1) and this is related to the use of Earth radiance reference spectra which reduces stripes. For GOME-2A, NO2 and HCHO SCD uncertainties increased by 7–9 and 11–15%year−1 respectively up until September 2009, when heating of the instrument markedly reduced further throughput loss, stabilising the degradation of SCD uncertainty to  < 3%year−1 for 2009–2015. Our work suggests that the NO2 SCD uncertainty largely consists of a random component ( ∼ 65% of the total uncertainty) as a result of the propagation of measurement noise but also of a substantial systematic component ( ∼ 35% of the total uncertainty) mainly from stripe effects. Averaging over multiple pixels in space and/or time can significantly reduce the SCD uncertainties. This suggests that trend detection in OMI, GOME-2 NO2, and HCHO time series is not limited by the spectral fitting but rather by the adequacy of assumptions on the atmospheric state in the later air mass factor (AMF) calculation step.

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Nitrogen dioxide and formaldehyde satellite data are used for air quality and climate studies. We quantify and characterise slant column uncertainties from different research groups. Our evaluation is motivated by recently improved techniques and by a desire to provide fully traceable uncertainty budget for climate records generated within the QA4ECV project. The improved slant columns are in agreement but with substantial differences in the reported uncertainties between groups and instruments.
Nitrogen dioxide and formaldehyde satellite data are used for air quality and climate studies....
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