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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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AMT | Articles | Volume 11, issue 11
Atmos. Meas. Tech., 11, 6189–6201, 2018
https://doi.org/10.5194/amt-11-6189-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Special issue: The 10th International Carbon Dioxide Conference (ICDC10)...

Atmos. Meas. Tech., 11, 6189–6201, 2018
https://doi.org/10.5194/amt-11-6189-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 15 Nov 2018

Research article | 15 Nov 2018

Calibration of isotopologue-specific optical trace gas analysers: a practical guide

David W. T. Griffith
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Cited articles  
Allison, C., Francey, R., and Meijer, H.: Recommendations for the reporting of stable isotope measurements for carbon and oxygen in CO2 gas, reference and Intercomparison Materials for stable isotopes of light element, IAEA-TECDO, IAEA, Vienna, 155–162, 1995. 
Bievre, P. D., Holden, N. E., and Barnes, I. L.: Isotopic Abundances and Atomic Weights of the Elements, J. Phys. Chem. Ref. Data, 809–891, 1984. 
Bowling, D. R., Sargent, S. D., Tanner, B. D., and Ehleringer, J. R.: Tunable diode laser absorption spectroscopy for stable isotope studies of ecosystem–atmosphere CO2 exchange, Agr. Forest Meteorol., 118, 1–19, https://doi.org/10.1016/S0168-1923(03)00074-1, 2003. 
Braden-Behrens, J., Yan, Y., and Knohl, A.: A new instrument for stable isotope measurements of 13C and 18O in CO2 – instrument performance and ecological application of the Delta Ray IRIS analyzer, Atmos. Meas. Tech., 10, 4537–4560, https://doi.org/10.5194/amt-10-4537-2017, 2017. 
Brand, W. A., Assonov, S. S., and Coplen, T. B.: Correction for the 17O interference in del(13C) measurements when analyzing CO2 with a stable isotope mass spectrometry (IUPAC Technical Report), Pure Appl. Chem., 82, 1719–1733, 2010. 
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In recent years optical spectroscopic techniques have become commonly used in the determination of mole fractions of trace gases in air. These techniques in many cases determine the mole fractions of only individual isotopic variants (isotopologues) of the trace gas, while for many applications the total mole fraction of all isotopologues is required. This paper sets out the measurements and calculations required to convert between individual isotopologue and total trace gas amounts.
In recent years optical spectroscopic techniques have become commonly used in the determination...
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