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Volume 11, issue 2 | Copyright
Atmos. Meas. Tech., 11, 881-893, 2018
https://doi.org/10.5194/amt-11-881-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 14 Feb 2018

Research article | 14 Feb 2018

Field measurements of biogenic volatile organic compounds in the atmosphere using solid-phase microextraction Arrow

Luís Miguel Feijó Barreira et al.
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Cited articles
Aalto, J., Kolari, P., Hari, P., Kerminen, V.-M., Schiestl-Aalto, P., Aaltonen, H., Levula, J., Siivola, E., Kulmala, M., and Bäck, J.: New foliage growth is a significant, unaccounted source for volatiles in boreal evergreen forests, Biogeosciences, 11, 1331–1344, https://doi.org/10.5194/bg-11-1331-2014, 2014.
Arneth, A., Harrison, S. P., Zaehle, S., Tsigaridis, K., Menon, S., Bartlein, P. J., Feichter, J., Korhola, A., Kulmala, M., and O'Donnell, D.: Terrestrial biogeochemical feedbacks in the climate system, Nat. Geosci., 3, 525–532, https://doi.org/10.1038/ngeo905, 2010.
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, 197–219, https://doi.org/10.1016/S1352-2310(03)00391-1, 2003.
Barreira, L. M. F., Parshintsev, J., Kärkkäinen, N., Hartonen, K., Jussila, M., Kajos, M., Kulmala, M., and Riekkola, M.-L.: Field measurements of biogenic volatile organic compounds in the atmosphere by dynamic solid-phase microextraction and portable gas chromatography-mass spectrometry, Atmos. Environ., 115, 214–222, https://doi.org/10.1016/j.atmosenv.2015.05.064, 2015.
Barreira, L. M. F., Xue, Y., Duporté, G., Parshintsev, J., Hartonen, K., Jussila, M., Kulmala, M., and Riekkola, M.-L.: Potential of needle trap microextraction-portable gas chromatography-mass spectrometry for measurement of atmospheric volatile compounds, Atmos. Meas. Tech., 9, 3661–3671, https://doi.org/10.5194/amt-9-3661-2016, 2016.
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Our results demonstrated the benefits and challenges of using new SPME Arrow over SPME fiber for the sampling of BVOCs emitted by terrestrial vegetation in the atmosphere. The new SPME Arrow system showed significant improvement on sampling capacity, with collected amounts being approximately 2 times higher for monoterpenes and 7–8 times higher for aldehydes than with SPME fiber. Higher extraction efficiencies were obtained with dynamic collection prior to equilibrium regime.
Our results demonstrated the benefits and challenges of using new SPME Arrow over SPME fiber for...
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