Articles | Volume 12, issue 3
https://doi.org/10.5194/amt-12-1429-2019
https://doi.org/10.5194/amt-12-1429-2019
Research article
 | 
05 Mar 2019
Research article |  | 05 Mar 2019

A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application

Thomas J. Bannan, Michael Le Breton, Michael Priestley, Stephen D. Worrall, Asan Bacak, Nicholas A. Marsden, Archit Mehra, Julia Hammes, Mattias Hallquist, M. Rami Alfarra, Ulrich K. Krieger, Jonathan P. Reid, John Jayne, Wade Robinson, Gordon McFiggans, Hugh Coe, Carl J. Percival, and Dave Topping

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Cited articles

Alfarra, M. R., Hamilton, J. F., Wyche, K. P., Good, N., Ward, M. W., Carr, T., Barley, M. H., Monks, P. S., Jenkin, M. E., Lewis, A. C., and McFiggans, G. B.: The effect of photochemical ageing and initial precursor concentration on the composition and hygroscopic properties of β-caryophyllene secondary organic aerosol, Atmos. Chem. Phys., 12, 6417–6436, https://doi.org/10.5194/acp-12-6417-2012, 2012. 
Alfarra, M. R., Good, N., Wyche, K. P., Hamilton, J. F., Monks, P. S., Lewis, A. C., and McFiggans, G.: Water uptake is independent of the inferred composition of secondary aerosols derived from multiple biogenic VOCs, Atmos. Chem. Phys., 13, 11769–11789, https://doi.org/10.5194/acp-13-11769-2013, 2013. 
Bannan, T. J., Booth, A. M., Jones, B. T., O'Meara, S., Barley, M. H., Riipinen, I., Percival, C. J., and Topping, D.: Measured Saturation Vapor Pressures of Phenolic and Nitro-aromatic Compounds, Environ. Sci. Technol., 51, 3922–3928, 2017. 
Bilde, M. and Pandis, S. N.: Evaporation rates and vapor pressures of individual aerosol species formed in the atmospheric oxidation of α-and β-pinene, Environ. Sci. Technol., 35, 3344–3349, 2001. 
Bilde, M., Svenningsson, B., Mønster, J., and Rosenørn, T.: Even-odd alternation of evaporation rates and vapor pressures of C3 C9 dicarboxylic acid aerosols, Environ. Sci. Technol., 37, 1371–1378, 2003. 
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Short summary
The Filter Inlet for Gases and AEROsols (FIGAERO) is an inlet designed to be coupled with a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) and provides simultaneous molecular information relating to both the gas- and particle-phase samples. This method has been used to extract vapour pressures of compounds whilst giving quantitative concentrations in the particle phase. Here we detail an ideal set of benchmark compounds for characterization of the FIGAERO.