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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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AMT | Articles | Volume 12, issue 2
Atmos. Meas. Tech., 12, 891–902, 2019
https://doi.org/10.5194/amt-12-891-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Special issue: Simulation chambers as tools in atmospheric research (AMT/ACP/GMD...

Atmos. Meas. Tech., 12, 891–902, 2019
https://doi.org/10.5194/amt-12-891-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 08 Feb 2019

Research article | 08 Feb 2019

Measurements of hydroperoxy radicals (HO2) at atmospheric concentrations using bromide chemical ionisation mass spectrometry

Sascha R. Albrecht et al.

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Short summary
Within this study we demonstrate reliable measurement of hydroperoxy (HO2) radicals via chemical ionisation mass spectrometry. HO2 is detected as an ion cluster with bromide ions, which allows a selective detection. This direct and sensitive measurement provides reliable data of HO2 radical concentrations in the atmosphere as demonstrated in the first application in simulation chamber experiments.
Within this study we demonstrate reliable measurement of hydroperoxy (HO2) radicals via chemical...
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