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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 5, issue 2 | Copyright
Atmos. Meas. Tech., 5, 363-375, 2012
https://doi.org/10.5194/amt-5-363-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 15 Feb 2012

Research article | 15 Feb 2012

A fast and precise chemiluminescence ozone detector for eddy flux and airborne application

A. Zahn1, J. Weppner1, H. Widmann1, K. Schlote-Holubek2, B. Burger2, T. Kühner2, and H. Franke3 A. Zahn et al.
  • 1Karlsruhe Institute of Technology (KIT), Institute for Meteorology and Climate Research (IMK), Karlsruhe, Germany
  • 2Karlsruhe Institute of Technology (KIT), Institute for Data Processing and Electronics (IPE), Karlsruhe, Germany
  • 3Enviscope GmbH, Frankfurt, Germany

Abstract. A commercially available dry chemiluminescence (CI) instrument for fast and precise measurement of ozone (O3) is specified. The sensitivity is ~9000 counts s−1 per ppbv of ozone. Its precision is entirely determined by the number of photons reaching the detector (being a photomultiplier), i.e. is quantum-noise limited. The relative precision (ΔO3/O3 in %) thus follows Poisson statistics and scales with the square root of the measurement frequency f and with the inverse O3 mixing ratio: ΔO3/O3f0.5 · O3−0.5. At typical O3 mixing ratios between 10 and 100 ppbv (and 1 bar), the precision is 0.3–1.0% at f = 10 Hz. The maximum measurement frequency is 50 Hz. The mechanical and electronic set-up as well as the instrument performance is described. Recommendations on the adequate inlet tube configuration (inlet tube length, sampling flow) and on the way of calibration at stationary ground-based platforms and onboard aircraft are given.

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