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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union

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Atmos. Meas. Tech., 6, 1095-1109, 2013
https://doi.org/10.5194/amt-6-1095-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
02 May 2013
Development of a cavity-enhanced absorption spectrometer for airborne measurements of CH4 and CO2
S. J. O'Shea1, S. J.-B. Bauguitte2, M. W. Gallagher1, D. Lowry3, and C. J. Percival1 1School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
2Facility for Airborne Atmospheric Measurements (FAAM), Building 125, Cranfield University, Cranfield, Bedford, MK43 0AL, UK
3Department of Earth Sciences, Royal Holloway, University of London, Egham, UK
Abstract. High-resolution CH4 and CO2 measurements were made on board the FAAM BAe-146 UK (Facility for Airborne Atmospheric Measurements, British Aerospace-146) atmospheric research aircraft during a number of field campaigns. The system was based on an infrared spectrometer using the cavity-enhanced absorption spectroscopy technique. Correction functions to convert the mole fractions retrieved from the spectroscopy to dry-air mole fractions were derived using laboratory experiments and over a 3 month period showed good stability. Long-term performance of the system was monitored using WMO (World Meteorological Office) traceable calibration gases. During the first year of operation (29 flights) analysis of the system's in-flight calibrations suggest that its measurements are accurate to 1.28 ppb (1σ repeatability at 1 Hz = 2.48 ppb) for CH4 and 0.17 ppm (1σ repeatability at 1 Hz = 0.66 ppm) for CO2. The system was found to be robust, no major motion or altitude dependency could be detected in the measurements. An inter-comparison between whole-air samples that were analysed post-flight for CH4 and CO2 by cavity ring-down spectroscopy showed a mean difference between the two techniques of −2.4 ppb (1σ = 2.3 ppb) for CH4 and −0.22 ppm (1σ = 0.45 ppm) for CO2. In September 2012, the system was used to sample biomass-burning plumes in Brazil as part of the SAMBBA project (South AMerican Biomass Burning Analysis). From these and simultaneous CO measurements, emission factors for savannah fires were calculated. These were found to be 2.2 ± 0.2 g (kg dry matter)−1 for CH4 and 1710 ± 171 g (kg dry matter)−1 for CO2, which are in excellent agreement with previous estimates in the literature.

Citation: O'Shea, S. J., Bauguitte, S. J.-B., Gallagher, M. W., Lowry, D., and Percival, C. J.: Development of a cavity-enhanced absorption spectrometer for airborne measurements of CH4 and CO2, Atmos. Meas. Tech., 6, 1095-1109, https://doi.org/10.5194/amt-6-1095-2013, 2013.
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