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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 8, issue 6
Atmos. Meas. Tech., 8, 2301-2313, 2015
https://doi.org/10.5194/amt-8-2301-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 8, 2301-2313, 2015
https://doi.org/10.5194/amt-8-2301-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 04 Jun 2015

Research article | 04 Jun 2015

A method for stable carbon isotope ratio and concentration measurements of ambient aromatic hydrocarbons

A. Kornilova et al.
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Revised manuscript under review for ACP
Stable carbon isotope ratios of ambient aromatic volatile organic compounds
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Subject: Gases | Technique: Laboratory Measurement | Topic: Validation and Intercomparisons
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Anderson, R., Czuba, E., Ernst, D., Huang, L., Thompson, A., and Rudolph, J.: Method for measuring carbon kinetic isotope effects of gas-phase reactions of light hydrocarbons with the hydroxyl radical, J. Phys. Chem. A, 107, 6191–6199, 2003.
Anderson, R., Huang, L., Iannone, R., Thompson, A., and Rudolph, J.: Carbon kinetic isotope effects in the gas phase reactions of light alkanes and ethene with the OH radical at 296 ± 4 K, J. Phys. Chem. A, 11537–11544, 2004.
Atkinson, R.: Atmospheric chemistry of VOCs and NOx, Atmos. Environ., 34, 2063–2101, 2000.
Bahlmann, E., Weinberg, I., Seifert, R., Tubbesing, C., and Michaelis, W.: A high volume sampling system for isotope determination of volatile halocarbons and hydrocarbons, Atmos. Meas. Tech., 4, 2073–2086, https://doi.org/10.5194/amt-4-2073-2011, 2011.
Bill, M., Conrad, M. E., and Goldstein, A. H.: Stable carbon isotope composition of atmospheric methyl bromide, Geophys. Res. Lett., 31, L04109, https://doi.org/10.1029/2003GL018639, 2004.
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Short summary
A technique for compound specific analysis of stable carbon isotope ratios and concentration of ambient volatile organic compounds (VOC) is presented. It is based on selective VOC sampling onto adsorbent filled cartridges. Examples of measurements conducted demonstrate that the ability to make accurate measurements in air with low VOC mixing ratios is important to avoid bias from an overrepresentation of samples that are strongly impacted by recent emissions.
A technique for compound specific analysis of stable carbon isotope ratios and concentration of...
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