Atmospheric Measurement Techniques
Atmospheric Measurement Techniques
AMT
Articles | Volume 8, issue 6
Articles | Volume 8, issue 6
https://doi.org/10.5194/amt-8-2577-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/amt-8-2577-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 8, issue 6
Research article
 | 
25 Jun 2015
Research article |  | 25 Jun 2015

The charging of neutral dimethylamine and dimethylamine–sulfuric acid clusters using protonated acetone

K. Ruusuvuori, P. Hietala, O. Kupiainen-Määttä, T. Jokinen, H. Junninen, M. Sipilä, T. Kurtén, and H. Vehkamäki

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Short summary
Ionization reagents suitable for accurate measurements of the atmospheric gas-phase amine vapour concentrations are needed. Based on computational results, acetone is a viable option for use as an ionization reagent in CI-APi-TOF measurements on atmospheric dimethylamine. However, comparison between the computational and experimental results revealed notable discrepancies. Further study is still required before the acetone CI-APi-TOF can be considered a viable option in practice.
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