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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 8, issue 7
Atmos. Meas. Tech., 8, 2737–2748, 2015
https://doi.org/10.5194/amt-8-2737-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 8, 2737–2748, 2015
https://doi.org/10.5194/amt-8-2737-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 08 Jul 2015

Research article | 08 Jul 2015

Efficient photochemical generation of peroxycarboxylic nitric anhydrides with ultraviolet light-emitting diodes

N. D. Rider et al.
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Cited articles  
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Darley, E. F., Kettner, K. A., and Stephens, E. R.: Analysis of Peroxyacyl Nitrates by Gas Chromatography with Electron Capture Detection, Anal. Chem., 35, 589–591, https://doi.org/10.1021/ac60197a028, 1963.
Day, D. A., Wooldridge, P. J., Dillon, M. B., Thornton, J. A., and Cohen, R. C.: A thermal dissociation laser-induced fluorescence instrument for in situ detection of NO2, peroxy nitrates, alkyl nitrates, and HNO3, J. Geophys. Res., 107, 4046, https://doi.org/10.1029/2001JD000779, 2002.
Fischer, E. V., Jaffe, D. A., Reidmiller, D. R., and Jaegle, L.: Meteorological controls on observed peroxyacetyl nitrate at Mount Bachelor during the spring of 2008, J. Geophys. Res., 115, D03302, https://doi.org/10.1029/2009JD012776, 2010.
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A photochemical source of peroxycarboxylic nitric anhydrides (PANs) in which a dialkyl ketone (acetone, diethyl-, di-isopropyl, or di-n-propyl ketone) in the presence of oxygen and nitric oxide is photodissociated by arrays of ultraviolet light-emitting diodes (UV-LEDs) is described. The source output was analyzed by gas chromatography and thermal dissociation cavity ring-down spectroscopy and modeled using the Master Chemical Mechanism.
A photochemical source of peroxycarboxylic nitric anhydrides (PANs) in which a dialkyl ketone...
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