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Volume 8, issue 9
Atmos. Meas. Tech., 8, 3851–3865, 2015
https://doi.org/10.5194/amt-8-3851-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: CHemistry and AeRosols Mediterranean EXperiments (ChArMEx)...

Atmos. Meas. Tech., 8, 3851–3865, 2015
https://doi.org/10.5194/amt-8-3851-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 21 Sep 2015

Research article | 21 Sep 2015

Intercomparison of two comparative reactivity method instruments inf the Mediterranean basin during summer 2013

N. Zannoni et al.
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Cited articles  
Ammann, C., Brunner, A., Spirig, C., and Neftel, A.: Technical note: Water vapour concentration and flux measurements with PTR-MS, Atmos. Chem. Phys., 6, 4643–4651, https://doi.org/10.5194/acp-6-4643-2006, 2006.
Archibald, A. T., Petit, A. S., Percival, C. J., Harvey, J. N., and Shallcross, D. E.: On the importance of the reaction between OH and RO2 radicals, Atmos. Sci. Lett., 10, 102–108, https://doi.org/10.1002/asl.216, 2009.
Atkinson, R., Aschmann, S. M., Winer, A. M., and Carter, W. P. L.: Rate constants for the gas phase reactions of OH radicals and O3 with pyrrole at 295 ± 1 K and atmospheric pressure, Atmos. Environ., 18, 2105–2107, https://doi.org/10.1016/0004-6981(84)90196-3, 1984.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III – gas phase reactions of inorganic halogens, Atmos. Chem. Phys., 7, 981–1191, https://doi.org/10.5194/acp-7-981-2007, 2007.
Bracho-Nunez, A., Welter, S., Staudt, M., and Kesselmeier, J.: Plant-specific volatile organic compound emission rates from young and mature leaves of Mediterranean vegetation, J. Geophys. Res.-Atmos., 116, D16304, https://doi.org/10.1029/2010JD015521, 2011.
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Our manuscript shows results of an intercomparison exercise conducted on two home-built comparative reactivity method (CRM) instruments operating under the same settings for measuring total OH reactivity. Despite the corrections of the raw data sets for instrumental artifacts having different weights on the two CRMs, we found very consistent results for the final processed data of ambient OH reactivity. Furthermore, we present in detail how to validate the instruments and process the raw data.
Our manuscript shows results of an intercomparison exercise conducted on two home-built...
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