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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 9, issue 3 | Copyright

Special issue: Limb observations of the middle atmosphere by space- and airborne...

Atmos. Meas. Tech., 9, 1051-1062, 2016
https://doi.org/10.5194/amt-9-1051-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 14 Mar 2016

Research article | 14 Mar 2016

Long-term validation of ESA operational retrieval (version 6.0) of MIPAS Envisat vertical profiles of methane, nitrous oxide, CFC11, and CFC12 using balloon-borne observations and trajectory matching

Andreas Engel1, Harald Bönisch1,a, Tim Schwarzenberger1,b, Hans-Peter Haase1,c, Katja Grunow2,d, Jana Abalichin2, and Stephan Sala1,e Andreas Engel et al.
  • 1Institute for Atmospheric and Environmental Sciences, Goethe Universität, Frankfurt, Germany
  • 2Institut für Meteorologie, Freie Universität Berlin, Berlin, Germany
  • anow at: Institut für Meteorologie und Klimaforschung, KIT, Karlsruhe, Germany
  • bnow at: Technologiezentrum Wasser, Karlsruhe, Germany
  • cnow at: Deka Bank, Frankfurt, Germany
  • dnow at: Senatsverwaltung für Stadtentwicklung und Umwelt, Berlin, Germany
  • enow at: Deutscher Wetterdienst, DWD, Offenbach, Germany

Abstract. MIPAS-Envisat is a satellite-borne sensor which measured vertical profiles of a wide range of trace gases from 2002 to 2012 using IR emission spectroscopy. We present geophysical validation of the MIPAS-Envisat operational retrieval (version 6.0) of N2O, CH4, CFC-12, and CFC-11 by the European Space Agency (ESA). The geophysical validation data are derived from measurements of samples collected by a cryogenic whole air sampler flown to altitudes of up to 34 km by means of large scientific balloons. In order to increase the number of coincidences between the satellite and the balloon observations, we applied a trajectory matching technique. The results are presented for different time periods due to a change in the spectroscopic resolution of MIPAS in early 2005. Retrieval results for N2O, CH4, and CFC-12 show partly good agreement for some altitude regions, which differs for the periods with different spectroscopic resolution. The more recent low spectroscopic resolution data above 20 km altitude show agreement with the combined uncertainties, while there is a tendency of the earlier high spectral resolution data set to underestimate these species above 25 km. The earlier high spectral resolution data show a significant overestimation of the mixing ratios for N2O, CH4, and CFC-12 below 20 km. These differences need to be considered when using these data. The CFC-11 results from the operation retrieval version 6.0 cannot be recommended for scientific studies due to a systematic overestimation of the CFC-11 mixing ratios at all altitudes.

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We present a validation of MIPAS-ENVISAT vertical profiles (ESA operational retrieval version 6.0) of N2O, CH4, CFC-12, and CFC-11. The geophysical validation is performed using data from a balloon-borne cryogenic whole air sampler and trajectory matching. We show that the validation results are different for the period prior to 2005 compared to the post 2005 period. N2O, CH4, and CFC-12 show partly good agreement while CFC-11 data from this retrieval cannot be used for scientific studies.
We present a validation of MIPAS-ENVISAT vertical profiles (ESA operational retrieval version...
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