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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 9, issue 3
Atmos. Meas. Tech., 9, 1325–1340, 2016
https://doi.org/10.5194/amt-9-1325-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 9, 1325–1340, 2016
https://doi.org/10.5194/amt-9-1325-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 30 Mar 2016

Research article | 30 Mar 2016

Challenges associated with the sampling and analysis of organosulfur compounds in air using real-time PTR-ToF-MS and offline GC-FID

Véronique Perraud et al.
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Atmos. Chem. Phys., 17, 11605–11621, https://doi.org/10.5194/acp-17-11605-2017,https://doi.org/10.5194/acp-17-11605-2017, 2017
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Andersen, K. B., Hansen, M. J., and Feilberg, A.: Minimisation of artefact formation of dimethyl disulphide during sampling and analysis of methanethiol in air using solid sorbent materials, J. Chromatogr. A, 1245, 24–31, 2012.
Andreae, M. O.: Ocean-Atmosphere interactions in the global biogeochemical sulfur cycle, Mar. Chem., 30, 1–29, 1990.
Andreae, T. W., Andreae, M. O., Bingemer, H. G., and Leck, C.: Measurements of dimethyl sulfide and H2S over the western north Atlantic and the tropical Atlantic, J. Geophys. Res., 98, 23389–23396, 1993.
Aneja, V. P.: Natural sulfur emissions into the atmosphere, J. Air Waste Manage., 40, 469–476, 1990.
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Short summary
Gas phase organosulfur compounds in air serve as precursors of particles which impact human health, visibility, and climate. We compare here two different approaches to measuring these compounds, one an online mass spectrometry technique and the other canister sampling followed by offline analysis by gas chromatography. We show that each approach has its own advantages and limitations in measuring these compounds in complex mixtures, including some artifacts due to reactions on surfaces.
Gas phase organosulfur compounds in air serve as precursors of particles which impact human...
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