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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 9, issue 4
Atmos. Meas. Tech., 9, 1449–1460, 2016
https://doi.org/10.5194/amt-9-1449-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 9, 1449–1460, 2016
https://doi.org/10.5194/amt-9-1449-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 04 Apr 2016

Research article | 04 Apr 2016

Characterization of the mass-dependent transmission efficiency of a CIMS

Martin Heinritzi et al.
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Cited articles  
Chernushevich, I. V., Loboda, A. V., and Thomson, B. A.: An introduction to quadrupole–time-of-flight mass spectrometry, J. Mass Spectrom., 36, 849–865, 2001.
Edwards, G. D., Cantrell, C. A., Stephens, S., Brian, H., Goyea, O., Shetter, R. E., Mauldin III, R. L., Kosciuch, E., Tanner, D. J. and Eisele, F. L.: Chemical Ionization Mass Spectrometer Instrument for the Measurement of Tropospheric HO2 and RO2, Anal. Chem., 75, 5317–5327, 2003.
Ehn, M., Junninen, H., Schobesberger, S., Manninen, H. E., Franchin, A., Sipilä, M., Petäjä, T., Kerminen, V.-M., Tammet, H., Mirme, A., Mirme, S., Hõrrak, U., Kulmala, M., and Worsnop D. R.: An Instrumental Comparison of Mobility and Mass Measurements of Atmospheric Small Ions, Aerosol Sci. Tech., 45, 522–532, 2011.
Eisele, F. L. and Tanner, D. J.: Ion-assisted tropospheric OH measurements, J. Geophys. Res., 96, 9295–9308, 1991.
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An easy-to-use method of estimating the mass-dependent transmission efficiency of a CIMS is presented. It makes use of depleting nitrate primary ions by different perfluorinated acids to obtain the transmission efficiency of these acids relative to the primary ion. Knowledge about the transmission efficiency is crucial for, e.g., quantification of extremely low volatile organic compounds.
An easy-to-use method of estimating the mass-dependent transmission efficiency of a CIMS is...
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