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Volume 9, issue 4
Atmos. Meas. Tech., 9, 1473–1484, 2016
https://doi.org/10.5194/amt-9-1473-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 9, 1473–1484, 2016
https://doi.org/10.5194/amt-9-1473-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 05 Apr 2016

Research article | 05 Apr 2016

Revisiting benzene cluster cations for the chemical ionization of dimethyl sulfide and select volatile organic compounds

Michelle J. Kim et al.
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Arnold, S. R., Spracklen, D. V., Williams, J., Yassaa, N., Sciare, J., Bonsang, B., Gros, V., Peeken, I., Lewis, A. C., Alvain, S., and Moulin, C.: Evaluation of the global oceanic isoprene source and its impacts on marine organic carbon aerosol, Atmos. Chem. Phys., 9, 1253–1262, https://doi.org/10.5194/acp-9-1253-2009, 2009.
Bandy, A. R.: Determination of the vertical flux of dimethyl sulfide by eddy correlation and atmospheric pressure ionization mass spectrometry (APIMS), J. Geophys. Res., 107, 4743, https://doi.org/10.1029/2002JD002472, 2002.
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Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical ionization of dimethyl sulfide (DMS) and a select group of volatile organic compounds (VOCs). Laboratory and field measurements were used to assess the sensitivity of the ionization scheme under a wide array of operating condition. Underway measurements of DMS in the North Atlantic were validated against an atmospheric pressure ionization mass spectrometer.
Benzene cluster cations were revisited as a sensitive and selective reagent ion for the chemical...
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