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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union
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Volume 9, issue 9
Atmos. Meas. Tech., 9, 4311–4325, 2016
https://doi.org/10.5194/amt-9-4311-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Meas. Tech., 9, 4311–4325, 2016
https://doi.org/10.5194/amt-9-4311-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 06 Sep 2016

Research article | 06 Sep 2016

Lake spray aerosol generation: a method for producing representative particles from freshwater wave breaking

Nathaniel W. May1, Jessica L. Axson2, Alexa Watson1, Kerri A. Pratt1,3, and Andrew P. Ault1,2 Nathaniel W. May et al.
  • 1Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA
  • 2Department of Environmental Health Sciences, University of Michigan, Ann Arbor, Michigan 48109, USA
  • 3Department of Earth and Environmental Sciences, University of Michigan, Ann Arbor, Michigan 48109, USA

Abstract. Wave-breaking action in bodies of freshwater produces atmospheric aerosols via a similar mechanism to sea spray aerosol (SSA) from seawater. The term lake spray aerosol (LSA) is proposed to describe particles formed by this mechanism, which have been observed over the Laurentian Great Lakes. Though LSA has been identified from size distribution measurements during a single measurement campaign, no measurements of LSA composition or relationship to bubble-bursting dynamics have been conducted. An LSA generator utilizing a plunging jet, similar to many SSA generators, was constructed for the generation of aerosol from freshwater samples and model salt solutions. To evaluate this new generator, bubble and aerosol number size distributions were measured for salt solutions representative of freshwater (CaCO3) and seawater (NaCl) at concentrations ranging from that of freshwater to seawater (0.05–35 g kg−1), synthetic seawater (inorganic), synthetic freshwater (inorganic), and a freshwater sample from Lake Michigan. Following validation of the bubble and aerosol size distributions using synthetic seawater, a range of salt concentrations were investigated. The systematic studies of the model salts, synthetic freshwater, and Lake Michigan sample indicate that LSA is characterized by a larger number size distribution mode diameter of 300 nm (lognormal), compared to seawater at 110 nm. Decreasing salt concentrations from seawater to freshwater led to greater bubble coalescence and formation of larger bubbles, which generated larger particles and lower aerosol number concentrations. This resulted in a bimodal number size distribution with a primary mode (180 ± 20 nm) larger than that of SSA, as well as a secondary mode (46 ± 6 nm) smaller than that of SSA. This new method for studying LSA under isolated conditions is needed as models, at present, utilize SSA parameterizations for freshwater systems, which do not accurately predict the different size distributions observed for LSA or resulting climate properties. Given the abundance of freshwater globally, this potentially important source of aerosol needs to be thoroughly characterized, as the sizes produced are relevant to light scattering, cloud condensation nuclei (CCN), and ice nuclei (IN) concentrations over bodies of freshwater.

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Aerosols are generated every time a wave breaks, as bubbles are formed that rise to the surface and burst. A great deal is known about sea spray aerosol from oceans, but very little is known about particles formed from freshwater, such as lakes and rivers. This study determines how "lake spray aerosol" is formed, which leads to distinctly different sizes and chemical composition from sea spray aerosol. These differences impact climate, weather, and human health near bodies of freshwater.
Aerosols are generated every time a wave breaks, as bubbles are formed that rise to the surface...
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